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The number concentration and properties of aerosol particles serving as cloud condensation nuclei (CCN) are important for understanding cloud properties, including in the tropical Atlantic marine boundary layer (MBL), where marine cumulus clouds reflect incoming solar radiation and obscure the low-albedo ocean surface. Studies linking aerosol source, composition, and water uptake properties in this region have been conducted primarily during the summertime dust transport season, despite the region receiving a variety of aerosol particle types throughout the year. In this study, we compare size-resolved aerosol chemical composition data to the hygrocopicity parameter κ derived from size-resolved CCN measurements made during the Elucidating the Role of Clouds-Circulation Coupling in Climate (EUREC4A) and Atlantic Tradewind Ocean-Atmosphere Mesoscale Interaction Campaign (ATOMIC) campaigns from January to February 2020. We observed unexpected periods of wintertime long-range transport of African smoke and dust to Barbados. During these periods, the accumulation-mode aerosol particle and CCN Number concentrations as well as the proportions of dust and smoke particles increased, whereas average κ slightly decreased (κ = 0.46 +/- 0.10) from marine background conditions (κ = 0.52 +/- 0.09) when the particles were mostly composed of marine organics and sulfate. Size-resolved chemical analysis shows that smoke particles were the major contributor to the accumulation mode during long-range transport events, indicating that smoke is mainly responsible for the observed increase in CCN number concentrations. Earlier studies conducted at Barbados have mostly focused on the role of dust in CCN, but our results show that aerosol hygroscopicity and CCN number concentrations during wintertime long-range transport events over the tropical North Atlantic are also affected by African smoke. Our findings highlight the importance of African smoke for atmospheric processes and cloud formation over the Caribbean. In the file “Dust_Mass_Conc_Royer2022” dust mass concentrations in grams per meter^3 are provided for each day of sampling. These data were used to generate Figure 2a in the manuscript. The file “Particle_Type_#fract_Royer2022” contains data obtained through CCSEM/EDX analysis and used to generate the temporal chemistry plot (Figure 4) provided in the manuscript. The data contains particle numbers for each particle type identified on stage 3 of the sampler, total particle numbers analyzed for the entire stage 3 sample, as well as particle number fractions in % values. In the file “Size-resolved_chem_Royer2022” we provide particle # and number fraction (%) values used to generate size-resolved chemistry plots in the manuscript (Figures 5a and 5b). The file includes all particle numbers and number fractions for sea salt, aged sea salt, dust+sea salt, dust, dust+smoke, smoke, sulfate, and organic particles in each size bin from 0.1 through 8.058 um during cumulative clean marine periods and CAT Event 1 as described in the manuscript. The file “K_at_0.16S_Royer2022” contains κ values calculated at 0.16% supersaturation (S) throughout the entire sampling period. These data were specifically used to generate the plot in Figure 7a. The file “CCN#_at_0.16S_Royer2022” contains cloud condensation nuclei (CCN) values calculated at 0.16% supersaturation (S) throughout the entire sampling period. These data were used to create the CCN portion of the plot in Figure 7b. 

Abstract. The number concentration and properties of aerosol particles serving ascloud condensation nuclei (CCN) are important for understanding cloudproperties, including in the tropical Atlantic marine boundary layer (MBL), where marine cumulus clouds reflect incoming solar radiation and obscure thelow-albedo ocean surface. Studies linking aerosol source, composition, andwater uptake properties in this region have been conducted primarily duringthe summertime dust transport season, despite the region receiving a varietyof aerosol particle types throughout the year. In this study, we comparesize-resolved aerosol chemical composition data to the hygroscopicityparameter κ derived from size-resolved CCN measurements made duringthe Elucidating the Role of Clouds–Circulation Coupling in Climate (EUREC4A) and Atlantic Tradewind Ocean-Atmosphere Mesoscale Interaction Campaign (ATOMIC) campaigns from January to February 2020. Weobserved unexpected periods of wintertime long-range transport of Africansmoke and dust to Barbados. During these periods, the accumulation-mode aerosol particle and CCN number concentrations as well as the proportions ofdust and smoke particles increased, whereas the average κ slightlydecreased (κ=0.46±0.10) from marine backgroundconditions (κ=0.52±0.09) when the submicron particles were mostly composed of marine organics and sulfate. Size-resolved chemicalanalysis shows that smoke particles were the major contributor to theaccumulation mode during long-range transport events, indicating that smokeis mainly responsible for the observed increase in CCN numberconcentrations. Earlier studies conducted at Barbados have mostly focused onthe role of dust on CCN, but our results show that aerosol hygroscopicity and CCN number concentrations during wintertime long-range transport events over the tropical North Atlantic are also affected by African smoke. Ourfindings highlight the importance of African smoke for atmospheric processesand cloud formation over the Caribbean. 

Abstract. Sea salt aerosols play an important role in the radiationbudget and atmospheric composition over the Arctic, where the climate israpidly changing. Previous observational studies have shown that Arctic sea ice leads are an important source of sea salt aerosols, and modeling efforts have also proposed blowing snow sublimation as a source. In this study,size-resolved atmospheric particle number concentrations and chemicalcomposition were measured at the Arctic coastal tundra site ofUtqiaġvik, Alaska, during spring (3 April–7 May 2016). Blowing snow conditions were observed during 25 % of the 5-week study period andwere overpredicted by a commonly used blowing snow parameterization based solely on wind speed and temperature. Throughout the study, open leads werepresent locally. During periods when blowing snow was observed, significantincreases in the number concentrations of 0.01–0.06 µm particles(factor of 6, on average) and 0.06–0.3 µm particles (67 %, on average) and a significant decrease (82 %, on average) in 1–4 µmparticles were observed compared to low wind speed periods. These size distribution changes were likely caused by the generation of ultrafineparticles from leads and/or blowing snow, with scavenging of supermicronparticles by blowing snow. At elevated wind speeds, both submicron andsupermicron sodium and chloride mass concentrations were enhanced,consistent with wind-dependent local sea salt aerosol production. Atmoderate wind speeds below the threshold for blowing snow as well as during observed blowing snow, individual sea spray aerosol particles were measured.These individual salt particles were enriched in calcium relative to sodiumin seawater due to the binding of this divalent cation with organic matter in the sea surface microlayer and subsequent enrichment during seawaterbubble bursting. The chemical composition of the surface snowpack alsoshowed contributions from sea spray aerosol deposition. Overall, theseresults show the contribution of sea spray aerosol production from leads onboth aerosols and the surface snowpack. Therefore, if blowing snowsublimation contributed to the observed sea salt aerosol, the snow beingsublimated would have been impacted by sea spray aerosol deposition rather than upward brine migration through the snowpack. Sea spray aerosol production from leads is expected to increase, with thinning and fracturingof sea ice in the rapidly warming Arctic.